A wave-mechanical treatment of the Mills-Nixon effect

The Mills-Nixon effect has been examined by a very simple wave-mechanical treatment. This has led to the conclusion that the effect of saturated side rings upon the ratio of the coefficients of the wave-functions of the two Kekulé structures is relatively small, being not more than about 6 per cent., and that the benzene ring retains the greater part of its stabilising resonance energy. Nevertheless, making the reasonable assumption that the ratio of the activation energies, for reaction as either one of the two Kekulé structures, depends upon the square of the ratio of coefficients, it is possible to account for the experimental facts. The effect which bending two valencies has upon the angles between the other valencies projecting from the benzene ring is found to be very small

Small Gas Turbine Combustor Primary Zone Study

The combustion research program, small gas turbine combustor primary zone study is summarized. The basic elements of a design methodology program to obtain the maximum performance potential of small reverse-flow annular combustors is described. Three preferred combustion design approaches for internal flame stabilization patterns were selected. Design features are incorporated in the combustors to address the performance limiting problem areas associated with smaller annular combustors. Performance is predicted by using a 3-D aerodynamic/chemical kinetic elliptic flow analysis, initially developed by Garrett Corporation for the USARTL. It is shown that the analytical flow field predictive models provide a useful design tool for understanding the combustion performance of a small reverse flow annular combustor

Spacecraft high-voltage power supply construction

The design techniques, circuit components, fabrication techniques, and past experience used in successful high-voltage power supplies for spacecraft flight systems are described. A discussion of the basic physics of electrical discharges in gases is included and a design rationale for the prevention of electrical discharges is provided. Also included are typical examples of proven spacecraft high-voltage power supplies with typical specifications for design, fabrication, and testing

Regenerable metallic oxide systems for removal of carbon dioxide: A concept

Design concepts for portable canisters for removal of carbon dioxide are described. One is screen pack configuration consisting of brazed rectangular canister with four metal oxide packs inserted. Other is radial flow canister with perforated central tube. Methods of production and operating principles are presented

Phosphonium chloride for thermal storage

Development of systems for storage of thermal energy is discussed. Application of phosphonium chloride for heat storage through reversible dissociation is described. Chemical, physical, and thermodynamic properties of phosphonium chloride are analyzed and dangers in using phosphonium chloride are explained

Solid amine compounds as sorbents for carbon dioxide: A concept

Solid amine compounds were examined as possible absorbents for removal of carbon dioxide in life support systems of type which may be employed in high altitude aircraft, spacecraft, or submarines. Many solid amine compounds release absorbed carbon dioxide when heated in vacuum, therefore, when properly packaged spent amine compounds can be readily regenerated and put back into service

Timing in trace conditioning of the nictitating membrane response of the rabbit (Oryctolagus cuniculus) : scalar, nonscalar, and adaptive features

Using interstimulus intervals (ISIs) of 125, 250, and 500 msec in trace conditioning of the rabbit nictitating membrane response, the offset times and durations of conditioned responses (CRs) were collected along with onset and peak latencies. All measures were proportional to the ISI, but only onset and peak latencies conformed to the criterion for scalar timing. Regarding the CR’s possible protective overlap of the unconditioned stimulus (US), CR duration increased with ISI, while the peak’s alignment with the US declined. Implications for models of timing and CR adaptiveness are discussed

Plans for the LIGO–TAMA joint search for gravitational wave bursts

We describe the plans for a joint search for unmodelled gravitational wave bursts being carried out by the LIGO and TAMA Collaborations using data collected during February–April 2003. We take a conservative approach to detection, requiring candidate gravitational wave bursts to be seen in coincidence by all four interferometers. We focus on some of the complications of performing this coincidence analysis, in particular the effects of the different alignments and noise spectra of the interferometers

Children's opinions on effective strategies to cope with bullying: the importance of bullying role and perspective

In order to find out what children would suggest as useful interventions to stop bullying, we designed a questionnaire administered to 311 children (155 boys and 156 girls; mean age = 11 years). Thirty-six items were employed to ask children how effective, in their opinion, retaliation, nonchalance and assertiveness could be in stopping bullying. Items were presented to children from three different perspectives (imagine you are the victim, the bully or a witness). We used peer reports to assess children's role in bullying. Children were grouped into bullies, followers of the bully, defenders of the victims, outsiders, victims and those not involved. The strategy most frequently chosen by all children was to cope with bullying through assertiveness. Bullies considered retaliation effective more often than their classmates, especially when they adopted the perspective of the victim or witness. Bullies did not consider assertive strategies as efficient in stopping the bully. Defenders, outsiders, victims and children not involved, on the other hand, were very much in favour of strategies aimed at solving the conflict through nonchalance or assertiveness, especially when they imagined being the bully. Girls chose assertive strategies more often than boys and younger children preferred nonchalance more often than older children, who tended to choose retaliation more often. Suggestions for intervention are made. © 2005 NFER